HSK 6
不料
búliào连
unexpectedly; to one's surprise
我刚出门不料又下起雨。
Wǒ gāng chū mén bú liào yòu xià qǐ yǔ.
I had just gone out when, unexpectedly, it began to rain again.
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New in the HSK 3.0 word list at level 6.